The properties of surface films on pyrite have been studied through electrochemical techniques of cyclic voltammetry and AC impedance measurements. The characteristics of the surface films depend on the conditions of oxidation and the source of pyrite. At potentials near 0.0 V, some pyrites have large values of polarization resistance, showing a certain degree of passivity. Some pyrites show more passivation than others, however. On oxidation, meta-stable phases of Fe(OH)2 and Fe(OH)3 form that transform to more stable phases on aging. The growth of surface films near the corrosion potential of pyrite follows a linear kinetics that is attributed to a chemical (or an electrochemical) reaction as the rate determining step. The surface film is considered to be a hydroxide or an oxide because it is hydrophilic. This study has also demonstrated that AC impedance ‘measurements can be used to study the growth characteristics of films at mineral/solution interfaces.