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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Chemical ...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Chemical Sciences
Article . 1997 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Solvent effects on reverse micellisation of Tween 80 and Span 80 in pure and mixed organic solvents

Authors: J Santhanalakshmi; S I Maya;

Solvent effects on reverse micellisation of Tween 80 and Span 80 in pure and mixed organic solvents

Abstract

Reverse micellisations of nonionic surfactants (Tween 80 and Span 80) in various pure nonaqueous solvents like carbontetrachloride, benzene, toluene, chloroform, cyclohexane and xylene, and in mixed solvent systems like CCl4-DMF and CCl4-DMSO covering the low dielectric range, are studied by UV electronic spectroscopy at 25°C. Micellar aggregation number (n s ) in various solvents is evaluated using the hydrophobic dye, Oil Red. 0. The critical micellar concentration (cmc) andn s ) dependencies on the solvent dielectric, solvent ionization potential, solvent-surfactant interaction potentials, mole fractions of solvents in mixtures and internal pressures are studied. The CCl4-DMSO system shows acmc increase effect, while the CCl4-DMF system shows acmc decrease effect and the excess functions of CCl4-DMSO and CCl4-DMF show increase and decrease effects respectively. Rationalisations of the results and the role of the solvent cage effect have been discussed.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Average
Top 10%
Average
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