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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Russian Journal of E...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Russian Journal of Electrochemistry
Article . 2000 . Peer-reviewed
License: Springer Nature TDM
Data sources: Crossref
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Relaxation spectra of the Warburg impedance and the constant-phase elements

Authors: M. G. Astaf’ev;

Relaxation spectra of the Warburg impedance and the constant-phase elements

Abstract

It is shown that there is indissoluble connection of impedances of constant-phase elements (CPE) with the presence, in a system, of a continuous spectrum of intrinsic frequencies inside a region where an impedance of CPE is observed. Such a connection exists in objects of any nature. As a result, the inevitable presence of the minimum limiting relaxation frequencies in real systems distorts the frequency characteristics of an ideal impedance of CPE in the zone where intrinsic frequencies are absent (restricts CPE). A transition zone of frequency characteristics of restricted CPE is studied. A false effect of the deviation of the CPE power index determined experimentally from a Nyquist plot from its true value is shown. A technique is proposed for restoring true values of CPE power indices and estimating limiting frequencies of relaxation spectra lying by many orders of magnitude lower than the minimum frequencies available for an experimental setup.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Average
Average
Average
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