Conductivity pre-exponential factors for some new superionic conductors

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1987 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of Materials Science, volume 9, pages 317-321 (issn: 0250-4707, eissn: 0973-7669,

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Authors: N B Desai; K Byrappa; G S Gopalakrishna; S Srikantaswamy; A B Kulkarni;

doi: 10.1007/bf02744012

Conductivity pre-exponential factors for some new superionic conductors

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Abstract

The pre-exponential factors obtained from the ionic conductivity studies on Na2(La, Al)ZrP3O12, Na2(La, Al)TiP3O12, NH4Zr2V3O12 and AlPO4:Li+ have been analysed. The compensation law has been found to be valid for these materials indicating that the entropy is directly related to the activation energy. The 1/α vsβ plots show straight lines for most of the superionic materials except for a few and this variation has been discussed.

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