
doi: 10.1007/bf02730336
Phenomenological field equations that describe isothermal chemical kinetics are cast into Hamiltonian form. The formalism is applied to a model reaction with autocatalytic chemicals in an extensive solution of substrate. Transforming the Hamiltonian into a collective representation shows that the autocatalytic subsystem can exist as a localized object with a discrete negative energy spectrum. It is observed that the collective state of matter exemplified by the model system also applies to other hypothetical reactions.
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