Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 2001 English Publisher:Springer Science and Business Media LLCJournal:Journal of Chemical Sciences, volume 113, pages 21-27 (issn: 0253-4134, eissn: 0973-7103,

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Authors: Subodh Kumar; R N Patel; P V Khadikar; K B PAndeya;

doi: 10.1007/bf02708548

Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

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Abstract

Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying pH values suggest that the imidazolate-bridged complex is stable over the pH-range 7.15–10.0.

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