Monoepoxidation of methyl linoleate: (±)‐methyl vernolate and (±)‐methyl coronarate

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1968 English Publisher:WileyJournal:Journal of the American Oil Chemists' Society, volume 45, pages 649-651 (issn: 0003-021X, eissn: 1558-9331,

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Authors: M. Ferrari; E. L. Ghisalberti; U. M. Pagnoni; F. Pelizzoni;

doi: 10.1007/bf02541248

Monoepoxidation of methyl linoleate: (±)‐methyl vernolate and (±)‐methyl coronarate

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Abstract

AbstractThe two monoepoxides resulting from the epoxidation of methyl linoleate with monoperphthalic acid have been separated from each other by column chromatography. Degradation reactions on each of these established that the separation occurred without concomitant rearrangement of the double bond or the epoxide ring. Thus, (±)‐methyl vernolate (I) and (±)‐methyl coronarate (II) were obtained in a pure state.

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