Cleavage of the carbon-carbon bond in α-glycols under the action of bismuth(v) derivatives

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1997 English Publisher:Springer Science and Business Media LLCJournal:Russian Chemical Bulletin, volume 46, pages 1,164-1,166 (issn: 1066-5285, eissn: 1573-9171,

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Authors: N. V. Dolganova; V. A. Dodonov; T. I. Zinov'eva; I. G. Prezhbog;

doi: 10.1007/bf02496220

Cleavage of the carbon-carbon bond in α-glycols under the action of bismuth(v) derivatives

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Abstract

Di(tert-butylperoxy)triphenylbismuth and the triphenylbismuth-tert-butyl hydroperoxide system react with 2,3-dimethylbutane-2,3-diol, benzopinacol, butane-2,3-diol, and ethane-1,2-diol with the cleavage of the C−C bond of α-glycol to form carbonyl compounds. Both heterolytic (through formation of cyclic triphenylbismuth glycolate) and homolytic cleavage occur.

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Yaroslav-the-Wise Novgorod State University
Russian Federation

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