Nitrosation of arenes with nitrosonium ethyl sulfate

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1999 English Publisher:Springer Science and Business Media LLCJournal:Russian Chemical Bulletin, volume 48, pages 506-509 (issn: 1066-5285, eissn: 1573-9171,

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Authors: N. V. Zyk; E. E. Nesterov; A. N. Khlobystov; N. S. Zefirov;

doi: 10.1007/bf02496170

Nitrosation of arenes with nitrosonium ethyl sulfate

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Abstract

Nitrosonium ethyl sulfate reacts withO-alkylphenols andN,N-dialkylanilines to give the corresponding 4-nitrosoarenes. The reaction is not accompanied by side processes characteristic of common nitrosating agents. Diazotization of primary aromatic amines with nitrosonium ethyl sulfate yields stable diazonium salts, which are promising reagents for organic synthesis.

Related Organizations

Lomonosov Moscow State University
Russian Federation

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