IR spectra of oxygen adsorbed on SnO2

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1975 English Publisher:Springer Science and Business Media LLCJournal:Reaction Kinetics and Catalysis Letters, volume 3, pages 63-70 (issn: 0133-1736, eissn: 1588-2837,

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Authors: T. A. Gundrizer; A. A. Davydov;

doi: 10.1007/bf02216890

IR spectra of oxygen adsorbed on SnO2

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Abstract

IR spectra of oxygen adsorbed on SnO2 with and without lattice defects have been studied. At low temperatures oxygen is adsorbed on defect SnO2 in two forms of O 2 − . This supports the earlier results obtained by ESR. The low-temperature forms of adsorbed oxygen (unrevealed in ESR spectra) were detected on defectless SnO2. High-temperature forms of adsorbed oxygen appear in the IR-spectra as bands due to vibrations of the cation-oxygen bond.

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Boreskov Institute of Catalysis
Russian Federation

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