
doi: 10.1007/bf02168901
pmid: 14879821
Allylazeton reagiert unter den Bedingungen einer milden Friedel-Craftschen Reaktion mit Naphthalin, wobei der Naphthylrest vorzugsweise an die wasserstoffarmere Seite der Allyl-Doppelbindung tritt. Analog reagiert Allyl-cyclohexanon mit Benzol. Die Produkte (I) bzw. (II) lassen sich durch Zyklisation und Dehydrierung in 1,4-Dimethyl-phenanthren (IV) bzw. in 9-Methyl-phenanthren (VIII) uberfuhren.
Phenanthrenes
Phenanthrenes
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