Butadiene polymerization over a π-allylnickel-alumina-silica gel catalyst system

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1980 English Publisher:Springer Science and Business Media LLCJournal:Reaction Kinetics and Catalysis Letters, volume 13, pages 319-322 (issn: 0133-1736, eissn: 1588-2837,

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Authors: W. Skupiński; M. Zawartke; St. Malinowski;

doi: 10.1007/bf02065693

Butadiene polymerization over a π-allylnickel-alumina-silica gel catalyst system

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Abstract

The relation between the activity and selectivity of a π-allyl-nickelalumina-silica gel catalyst system and the SiO2 content of the support has been studied. Higher activity of systems containing mixed gels was ascertained. The selectivity to poly (1,4-cis-butadiene) increases, whereas that to the 1,4-trans isomer markedly decreases with increasing SiO2 concentration. Over catalysts based on either Al2O3 or SiO3, only poly-(1,4-trans-butadiene) (97%) was obtained.

Related Organizations

Institute of Organic Chemistry
Poland
Polish Academy of Sciences
Poland

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