Selective hydrogenation of dehydrolinalool and dehydrolinalyl acetate to linalool and linalyl acetate

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1981 English Publisher:Springer Science and Business Media LLCJournal:Reaction Kinetics and Catalysis Letters, volume 16, pages 265-270 (issn: 0133-1736, eissn: 1588-2837,

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Authors: A. M. Pak; O. I. Kartonozhkina; A. P. Pogorelskii; E. M. Tsai; D. V. Sokolskii;

doi: 10.1007/bf02065470

Selective hydrogenation of dehydrolinalool and dehydrolinalyl acetate to linalool and linalyl acetate

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Abstract

Hydrogenation of dehydrolinalool and dehydrolinalyl acetate on 0.5% Pd/Al2O3 in C2–C5 alcohols of various structure has been studied at atmospheric and higher pressures of hydrogen. It is shown that the differences in selectivity of hydrogenation of dehydrolinalool to linalool and of dehydrolinalyl acetate to linalyl acetate is due to peculiarities in their structure.

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