The EFG in oxonium ferric orthophosphate hydrate and related compounds

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1988 English Publisher:Springer Science and Business Media LLCJournal:Hyperfine Interactions, volume 40, pages 311-313 (issn: 0304-3843, eissn: 1572-9540,

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Authors: W. Meisel;

doi: 10.1007/bf02049105

The EFG in oxonium ferric orthophosphate hydrate and related compounds

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Abstract

The point cherge model was used to interpret the small quadrupole spilting of Fe3H15(PO4)8·5H2O by comparing it with related phosphates of known structure. The approximation is sufficient as long as octahedrally coordinated compounds are compared for which Vzz and η do not change their signs.

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Johannes Gutenberg University of Mainz
Germany

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