Advanced isoconversional method

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1997 English Publisher:Springer Science and Business Media LLCJournal:Journal of Thermal Analysis, volume 49, pages 1,493-1,499 (issn: 0368-4466,

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Authors: S. Vyazovkin;

doi: 10.1007/bf01983708

Advanced isoconversional method

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Abstract

A nonlinear algorithm has been suggested to increase the accuracy of evaluating the activation energy by the integral isoconversional method. A minor modification of the algorithm has made it possible to adapt the isoconversional method for an arbitrary variation of the temperature. This advanced isoconversional method allows for trustworthy estimates of the activation energy when the thermal effect of a reaction makes the temperature of a sample deviate from a prescribed heating program.

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University of Utah
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