Complexes of acid amides with aprotic polar solvents IV. Complexes of poly(acid amides) with aprotic solvents

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1983 English Publisher:Springer Science and Business Media LLCJournal:Journal of Thermal Analysis, volume 27, pages 333-340 (issn: 0368-4466, eissn: 1572-8943,

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Authors: Yu. N. Sazanov; L. A. Shibaev; T. I. Zhukova; N. G. Stepanov; S. A. Dauengauer; T. M. Bulina;

doi: 10.1007/bf01914670

Complexes of acid amides with aprotic polar solvents IV. Complexes of poly(acid amides) with aprotic solvents

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Abstract

The process of solid-phase cyclodehydration of films cast from solutions of poly(acid amides) (PAA) in dimethylformamide, dimethylacetamide and N-methyl-2-pyrrolidone has been investigated by mass-spectrometric thermal analysis (MTA). It is shown that MTA is a structure-sensitive method making it possible to follow the appearance and changes in the character of ordered structures formed in PAA films. The authors relate these structures to the process of crystallization of complexes of PAA with aprotic polar solvents.

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Russian Academy of Sciences
Russian Federation

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