
doi: 10.1007/bf01913186
Polystyrene (PS) and its copolymers (SBR, ASA, SAN and ABS) have been studied by differential thermal analysis. These five families exhibit a large endothermic decomposition peak at about 380 °C. The curves exhibit also one exothermic peak (ASA, SAN, ABS) or two (PS, SBR) which are larger and nearer for SBR than for PS. ASA, SAN and ABS copolymers are characterized by an endothermic peak shape (the slope of the ascending part has been computed and expressed for one gramme of sample). This method was used for identification of alimentary package and some pharmaceutical disposables. Polystyren (PS) und dessen Copolymere (SBR, ASA, SAN und ABS) wurden mittels DTA untersucht. Diese 5 Systeme ergeben einen starken endothermen Zersetzungspeak bei 380 °C. Die Kurven weisen auch einen (ASA, SAN, ABS) bzw. zwei (PS, SBR) exotherme Peaks auf, die bei SBR groser und naher bei einander sind als bei PS. Fur ASA-, SAN- und ABS-Copolymere ist die Form des endothermen Peaks charakteristisch (die Steigung des Kurvenastes ansteigender Temperatur wurde berechnet und bezogen auf 1 g der Probe angegeben). Diese Methode wurde zur Identifizierung von Verpackungsmaterial von Lebensmitteln und Arzneimitteln herangezogen. Методом ДТА изучены п олистирол (PS) и его сополимеры (SBR, ASA, SAN и ABS). Все пять полимеров да ют при 380° большой эндотермический пик разложения. Кривые ДТ А для соединений ASA, SAN, ABS показыв ают один экзотермиче ский пик, а для соединений PS, SBR два пика, которые для соед инения SBR больше и уже, ч ем для PS. Сополимеры ASA, SAN и ABS охарактеризованы фо рмой эндотермическо го пика (вычислен наклон крив ой с увеличением температуры и выраже н на грамм вещества). Эт от метод был использован для и дентификации упаковки пищевых и фа рмацевтических прод уктов.
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