
doi: 10.1007/bf01911412
The theory of Borchardt and Daniels for the determination from the DTA curve of the fraction decomposed (α) is used. The probable mechanism, activation energy (E) and frequency factor (Z) can be found by the trial and error method from the plot ofα vs.T for a decomposition reaction which can be expressed by the equation $$\log g(\alpha ) = \log p(E/RT) + \frac{{ZE}}{{Rq}}$$
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