
doi: 10.1007/bf01900375
pmid: 5412287
Es wird die katalytische Deaminierung des Asparagins mittels Cu++ bei 80°–100°C beschrieben. In diesem Temperaturbereich findet die Reaktion auch in Losungen statt, wahrend die Katalyse im Trockenruckstand bedeutend starker ist. Die optimale Konzentration des Cu++ (bezogen auf das Asparagin) ist 1∶4M. Unter den gunstigsten Bedingungen werden 20% des Asparagins zu Asparaginsaure deaminiert.
Chromatography, Paper, Amines, Asparagine, Catalysis, Copper
Chromatography, Paper, Amines, Asparagine, Catalysis, Copper
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