Theoretical analysis of oriented and non-isothermal crystallization III. Kinetics of crystal orientation

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 1978 English Publisher:Springer Science and Business Media LLCJournal:Colloid and Polymer Science, volume 256, pages 332-342 (issn: 0303-402X, eissn: 1435-1536,

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Authors: Andrzej Ziabicki; Leszek Jarecki;

doi: 10.1007/bf01544326

Theoretical analysis of oriented and non-isothermal crystallization III. Kinetics of crystal orientation

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Abstract

A general orientation equation for rigid particles embedded in a continuum has been derived. The equation includes hydrodynamic, thermodynamic, diffusional and kinetic terms, corresponding to physically different orientation mechanisms. Some special solutions of the general equation are presented, and discussed conditions under which the general equation reduces to more simple cases. Numerical examples of orientation in polyethylene subjected to uniaxial forces are discussed.

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