1,2,3-Triaminoguanidinium azide (TAZ) structure

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1990 English Publisher:Springer Science and Business Media LLCJournal:Journal of Crystallographic and Spectroscopic Research, volume 20, pages 31-35 (issn: 0277-8068, eissn: 1572-8854,

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Authors: A. J. Bracuti; M. W. Extine;

doi: 10.1007/bf01181672

1,2,3-Triaminoguanidinium azide (TAZ) structure

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Abstract

Triaminoguanidinium azide (TAZ) crystallizes in the monoclinic space group P21/c witha=6.679(2),b=7.722(2),c=13.143(4) A,β=95.44(2)°,Z=4, with one anion/cation pair in the asymmetric unit. The structure was solved by direct methods and refined to a finalR value of 0.037. The non-hydrogen atoms of the triaminoguanidinium cation are planar and the azide anion is linear. This puckered layer structure consists of an infinite three-dimensional network of N-H⋯N hydrogen bonds which link the cations to the anions.

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