Transformation of cyclic alcohols on neodymium oxide

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1964 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences, USSR Division of Chemical Science, volume 13, pages 10-13 (issn: 0568-5230, eissn: 1573-9171,

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Authors: Kh. M. Minachev; M. A. Markov; V. I. Bogomolov; F. �. �nglina;

doi: 10.1007/bf01179558

Transformation of cyclic alcohols on neodymium oxide

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Abstract

1. The conversion of cyclohexanol at 200–500°, cyclopentanol and methylcyclohexanols at 350° on Nd2O3 was investigated in a circulating-type system in a stream of nitrogen. 2. The activation energy of the dehydration of cyclohexanol on Nd2O3 (determined without dilution with nitrogen) at 230–286° is 23.3 kcal/mole. 3. Cyclopentanol, cyclohexanol, and methylcyclohexanols are dehydrated to the same degree on Nd2O3 at 350° the hydrocarbon portion of the catalyzates obtained from the methylcyclohexanols containing only products of direct dehydration of the alcohols.

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Russian Academy of Sciences
Russian Federation

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