Polyenic compounds Communication 2. Polyenic compounds containing heterocyclic substituents

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1956 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 5, pages 1,489-1,492 (issn: 0568-5230, eissn: 1573-9171,

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Authors: B. M. Mikhailov; G. S. Ter-Sarkisyan;

doi: 10.1007/bf01177529

Polyenic compounds Communication 2. Polyenic compounds containing heterocyclic substituents

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Abstract

1. In the reactions of 2-pyridylmethyllithium and of 2-quinolylmethyllithium with 3-methyl-6-phenyl-3, 5-hexadien-2-one, the corresponding tertiary alcohols were formed. Dehydration of these gave 2, 3-dimethyl-6-phenyl-1-(2-pyridyl)-1, 3, 5-hexatriene and 2, 3-dirnethyl-6-phenyl-1-(2-quinolyl)-1, 3, 5-hexatriene. 2. Reaction of 2-pyridylmethyllithium and of 2-quinolylmethyllithium with cinnamaldehyde gave the butenols 4-phenyl-1-(2-pyridyl)-3-buten-2-o1 and 4-phenyl-1-(2-quinolyl)-3-buten-2-o1. 'Dehydration of these gave butadiene derivatives.

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Russian Academy of Sciences
Russian Federation

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