Structure and IR spectroscopic properties ofN-methylmorpholinium pentachlorophenolate-pentachlorophenol

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 1990 English Publisher:Springer Science and Business Media LLCJournal:Journal of Crystallographic and Spectroscopic Research, volume 20, pages 187-192 (issn: 0277-8068, eissn: 1572-8854,

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Authors: I. Majerz; Z. Malarski; T. Lis;

doi: 10.1007/bf01160973

Structure and IR spectroscopic properties ofN-methylmorpholinium pentachlorophenolate-pentachlorophenol

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Abstract

The crystal structure of C5H11OND+C6Cl5O−·C6Cl5OD has been determined by X-ray diffraction. The crystals are triclinic:P¯1,a=9.443(7),b=7.534(6),c=18.05(2) A,α=91.23(7),β=95.83(6), γ=110.67(6)°,Z=2. The structure was solved by direct methods, and refined toR=0.033 for 2779 non-zero reflections. The structure consists of theN-methylmorpholinium cations and deuterium bis(pentachlorophenolate) homoconjugated anions. The N+-D(1)⋯O(l)− and O(2)-D(2)⋯O(1)− bond lengths and angles are 2.654(4), 2.557(4) A, and 171(4), 158(5)°, respectively.

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University of Wrocław
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