Reactions of lithium-biphenyl adducts with carbonyl compounds

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1966 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences, USSR Division of Chemical Science, volume 15, pages 1,384-1,386 (issn: 0568-5230, eissn: 1573-9171,

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Authors: E. P. Kaplan; Z. I. Kazakova; E. D. Lubuzh; A. D. Petrov;

doi: 10.1007/bf01151377

Reactions of lithium-biphenyl adducts with carbonyl compounds

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Abstract

1. The reactions of lithium-biphenyl adducts in tetrahydrofuran solution with acetaldehyde, benzaldehyde, acetone, cyclohexanone, and ethyl octanoate were carried out. 2. The reaction of lithium-biphenyl adducts with carbonyl compounds takes two courses: condensation of the carbonyl compounds, and organolithium synthesis with formation of alcohols and diols.

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Russian Academy of Sciences
Russian Federation

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