Decomposition of benzenediazonium fluoborate in benzenesulfonic esters and in acetophenone

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1958 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 7, pages 548-551 (issn: 0568-5230, eissn: 1573-9171,

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Authors: L. G. Makarova; M. K. Matveeva;

doi: 10.1007/bf01151324

Decomposition of benzenediazonium fluoborate in benzenesulfonic esters and in acetophenone

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Abstract

1. Phenyl formed by the decomposition of benzenediazonium fluoborate in methyl and ethyl benzenesulfonates acts only on the alkoxysulfonyl group in these esters and in both cases gives phenyl benzenesulfonate. 2. In the decomposition of benzenediazonium fluoborate in acetophenone, 3′- and 4′-phenylacetophenones are formed in the ratio of 4∶1. 3. These reactions constitute proof of the heterolytic character of the decomposition of benzenediazonium fluoborate.

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Russian Academy of Sciences
Russian Federation

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