The intercalation of phenylethylamines intoα-zirconium phosphate has been investigated by the pH titration method.dl-1-Phenylethylamine (dl-PEA) is taken up in two stages. New phases were obtained: Zr(HPO4)2(dl-PEA) · H2O in the first, and Zr(HPO4)2(dl-PEA)/43· H2O in the second stage. 2-Phenylethylamine (2-PEA) also is loaded in two stages, but the first end point is not observed clearly. A new phase, Zr(HPO4)2(2-PEA)2 · H2O has been formed at the second stage. The new phases have been characterized by elemental analysis, X-ray diffractometry, thermal analysis and IR spectroscopy.