Hammett constants of some (Trialkylsilyl)alkyl groups

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1961 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 10, pages 419-423 (issn: 0568-5230, eissn: 1573-9171,

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Authors: E. A. Chernyshev; N. G. Tolstikova;

doi: 10.1007/bf01131058

Hammett constants of some (Trialkylsilyl)alkyl groups

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Abstract

1. The results confirm that in various phenylsilanes silicon can occur in the Si−(V) state on account of free 3d orbitals. 2. The specific effect of a silicon atom on β-functional groups is clearly determined by the specific character of the structure of these compounds together with the induction effects of the silyl and functional groups.

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Russian Academy of Sciences
Russian Federation

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