Enantiomeric synthesis of dominicalure, aggregation pheromone of lesser grain borer,Rhyzopertha dominica (F.)

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1990 English Publisher:Springer Science and Business Media LLCJournal:Journal of Chemical Ecology, volume 16, pages 1,921-1,925 (issn: 0098-0331, eissn: 1573-1561,

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Authors: L, Lin-Yu; L, Guo-Qiang;

doi: 10.1007/bf01020505

pmid: 24263995

Enantiomeric synthesis of dominicalure, aggregation pheromone of lesser grain borer,Rhyzopertha dominica (F.)

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Abstract

(S)-(+)-1-Methylbutyl (E)-2-methyl-2-pentenoate,1, and (S)-(+)-1-methylbutyl (E)-2,4-dimethyl-2-pentenoate2, the aggregation pheromone for lesser grain borerRhyzopertha dominica (F). were synthesized from crotylaldehyde in an overall yield of 30%. The chiral intermediate6 was prepared in 90% enantiomer excess, employing the Sharpless asymmetric epoxidation.

Related Organizations

Academia Sinica
Taiwan
Shanghai Institute of Organic Chemistry
China (People's Republic of)
Chinese Academy of Sciences
China (People's Republic of)

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