Reaction of allene cyclodimers with alkyllithium compounds

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1988 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 37, pages 1,785-1,788 (issn: 0568-5230, eissn: 1573-9171,

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Authors: A. V. Yurkovetskii; G. N. Bondarenko; V. D. Oppengeim; K. L. Makovetskii;

doi: 10.1007/bf00962488

Reaction of allene cyclodimers with alkyllithium compounds

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Abstract

1,3-Dimethylenecyclobutane and 1-methyl-3-methylenecyclobutene are metallated in the presence of THF by alkyllithium compounds under mild conditions with the formation of one and the same organolithium compound of the π-pentadienyl type. Under the same conditions, 1,2-dimethylenecyclobutane adds alkyllithium compounds, to form a π-alkenyl complex.

Related Organizations

Russian Academy of Sciences
Russian Federation
A.V.Topchiev Institute of Petrochemical Synthesis
Russian Federation

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