Water-gas shift reaction in the liquid phase: Catalysis by water-soluble rhodium complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1989 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 38, pages 476-482 (issn: 0568-5230, eissn: 1573-9171,

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Authors: E. G. Chepaikin; A. P. Bezruchenko; E. N. Sal'nikova; F. Io; Z. Tom; M. T. Beck; M. L. Khidekel';

doi: 10.1007/bf00958036

Water-gas shift reaction in the liquid phase: Catalysis by water-soluble rhodium complexes

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Abstract

1. A series of water-soluble rhodium complexes containing diphenyl-m-sulfophenylphosphine as ligand are synthesized. The catalytic activity of the synthesized complexes in the WGSR is studied. 2. Probable mechanistic schemes for the WGSR are proposed, including intermediates not containing halide ions.

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Russian Academy of Sciences
Russian Federation

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