Mass spectrometry of ?-complexes of transition metals. Communication 32. Derivatives of ?-cyclopentadienyl-?-(3)-1,2-dicarbollyliron(III)

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1984 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 33, pages 2,048-2,052 (issn: 0568-5230, eissn: 1573-9171,

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Authors: N. I. Vasyukova; D. V. Zagorevskii; V. V. Kobak; A. I. Kovredov; L. I. Zakharkin;

doi: 10.1007/bf00954079

Mass spectrometry of ?-complexes of transition metals. Communication 32. Derivatives of ?-cyclopentadienyl-?-(3)-1,2-dicarbollyliron(III)

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Abstract

The basic paths have been established in the fragmentation of derivatives of π-cyclopentadienyl-π-(3)-1,2-dicarbollyliron(III) under electron impact: cleavage of the carbollyl-Fe bond, deep dehydrogenation, dehydration, and dehydrohalogenation. The carbollyl complexes are less stable to electron impact thatn are the ferrocene derivatives. In the molecular ions, the Cp-Fe bond is stronger than the carbollyl-Fe bond.

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Russian Academy of Sciences
Russian Federation

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