Synthesis of 2-alkyl(aryl)-cis-1-thiahydrindanes

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1988 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 37, pages 2,118-2,122 (issn: 0568-5230, eissn: 1573-9171,

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Authors: N. P. Volynskii; L. A. Zegel'man; M. B. Smirnov;

doi: 10.1007/bf00953417

Synthesis of 2-alkyl(aryl)-cis-1-thiahydrindanes

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Abstract

1. cis- and trans-2-Alkyl(aryl)-cis-1-thiahydrindanes have been obtained for the first time free from traces of structural isomers. 2. cis-1-Thiahydrindane and trans-2-alkyl(aryl)-cis-1-thiahydrindanes are present in solution predominantly in conformations in which H9 is equatorial in the cyclohexane ring, whereas cis-2-alkyl(aryl)-cis-1-thiahydrindanes have the conformation in which H9 is axial.

Related Organizations

Russian Academy of Sciences
Russian Federation
A.V.Topchiev Institute of Petrochemical Synthesis
Russian Federation

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