Vibrational spectrum of hexamethylcyclotrisiloxane and the dynamic parameters of dimethylpolysiloxanes

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 1989 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 38, pages 767-772 (issn: 0568-5230, eissn: 1573-9171,

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Authors: T. F. Tenisheva;

doi: 10.1007/bf00953289

Vibrational spectrum of hexamethylcyclotrisiloxane and the dynamic parameters of dimethylpolysiloxanes

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Abstract

1. The vibrational frequencies of the hexamethylcyclotrisiloxane molecule are in good agreement with the calculated values based on the force field of the O2Si(CH3)2 segment as calculated from the experimental spectrum of dimethyldimethoxylsilane. 2. The force field of the O2Si(CH3)2 segment can be used to construct an initial approximation of the force fields of various dimethylpolysiloxane oligomers and polymers in spectroscopic and thermodynamic calculations.

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Russian Academy of Sciences
Russian Federation

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