Electronic mechanism of catalytic dehydration of ethanol

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1983 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 32, pages 1,140-1,145 (issn: 0568-5230, eissn: 1573-9171,

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Authors: S. G. Gagarin; R. Z. Zakharyan; Yu. A. Kolbanovskii;

doi: 10.1007/bf00953144

Electronic mechanism of catalytic dehydration of ethanol

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Abstract

1. On the basis of an analysis of the distribution of the deforming force among the atoms and bonds during electronic transitions it was shown that the dehydration of ethanol is promoted by capture of an electron from the catalyst by the adsorbed molecule. 2. An electronic mechanism is substantiated for the dehydration of alcohol at aluminum oxide in the reaction of the molecule with an active center of the surface containing a localized electron or in interaction with a molecule of the reaction product adsorbed at an analogous center.

Related Organizations

Russian Academy of Sciences
Russian Federation
A.V.Topchiev Institute of Petrochemical Synthesis
Russian Federation

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