Vinyl derivatives of thiocaprolactam

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1969 English Publisher:Springer Science and Business Media LLCJournal:Chemistry of Heterocyclic Compounds, volume 3, pages 415-417 (issn: 0009-3122, eissn: 1573-8353,

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Authors: F. P. Sidel'kovskaya; A. A. Avetisyan; M. G. Zelenskaya; M. F. Shostakovskii;

doi: 10.1007/bf00945381

Vinyl derivatives of thiocaprolactam

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Abstract

A study is made of the reaction of N-vinylcaprolactam with phosphorus pentasulfide. When the reaction is run in xylene, thiocaprolactam is isolated, when Na2CO3 is present, or pyridine, a dimer of N-vinylcaprolactam is formed. As a result of a study of the reaction of thiocaprolactam with acetylene under various conditions, a method is devloped for synthesizing new sulfur- and nitrogen-containing monomers of N-vinylthiocaprolactam and S-vinylthiocaprolactam.

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