Complexes of nickel(II) and palladium(II) with thiobenzamide

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1979 English Publisher:Springer Science and Business Media LLCJournal:Transition Metal Chemistry, volume 4, pages 46-48 (issn: 0340-4285, eissn: 1572-901X,

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Authors: Andr� J. Aarts; Herman O. Desseyn; Medard A. Herman;

doi: 10.1007/bf00941017

Complexes of nickel(II) and palladium(II) with thiobenzamide

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Abstract

The electronic and vibrational spectra of NiII and PdII complexes with thiobenzamide, L, are discussed. L acts as a sulphur donor ligand. The PdII compounds and (NiL4)(ClO4)2 are square planar. PdL2Cl2 has acis-structure, while PdL2X2 (X=Br or I) istrans; NiL4Cl2 istrans-octahedral. The i.r. bands due toν(M.S) andν(MX) have been assigned. The influence of the anions on the properties of the complexes, both in solution and in the solid state, is discussed.

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University Centre Saint-Ignatius Antwerp
Belgium

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