Anodic oxidation of olefins in presence of fluorine anion

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1976 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 25, pages 1,361-1,363 (issn: 0568-5230, eissn: 1573-9171,

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Authors: I. N. Rozhkov; I. Ya. Aliev; I. L. Knunyants;

doi: 10.1007/bf00928099

Anodic oxidation of olefins in presence of fluorine anion

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Abstract

1. The anodic oxidation of olefins in the presence of fluorine anion can be accompanied by the addition of two fluorine atoms to the multiple bond. Allylic substitution is a more characteristic reaction in the anodic oxidation of olefins. 2. The high lability of the allylic and benzylic fluorine atoms in acid medium is the reason for the formation of acetamides during the anodic oxidation of olefins in a solution of tetraethylammonium fluoride hydrofluoride in acetonitrile.

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Russian Academy of Sciences
Russian Federation

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