Electrophilic mercuration of carboranes

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1977 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 26, pages 1,747-1,750 (issn: 0568-5230, eissn: 1573-9171,

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Authors: L. I. Zakharkin; I. V. Pisareva;

doi: 10.1007/bf00925193

Electrophilic mercuration of carboranes

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Abstract

1. The o- and m-carboranes undergo electrophilic polymercuration by mercury fluoroacetate in trifluoroacetic acid at the boron atoms to give the pentamercury-substituted o-carboranes and trimercury-substituted m-carboranes. 2. The electrophilic monomercuration of o-carborane proceeds in the 9(12) and 8(10) positions of the o-carborane nucleus, while the electrophilic mono- and dimercuration of m-carborane proceed predominantly in the 9 and 10 position of the m-carborane nucleus.

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Russian Academy of Sciences
Russian Federation

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