
doi: 10.1007/bf00922975
1. The reaction of Al(BH4)3 with the unsolvated Ca(BH4)2 gave the complex Ca(BH4)2·Al(BH4)3, which is stable at room temperature; its density and IR spectrum are given. 2. Ca(BH4)2·Al(BH4)3 decomposes completely into the component borohydrides when heated in vacuo or when treated with donor solvents. The complex apparently has the structure [CaBH4]+[Al(BH4)4]− after treatment with octane.
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