Mechanism of the oxidation of cellulose with nitrogen oxides

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1959 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 8, pages 316-321 (issn: 0568-5230, eissn: 1573-9171,

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Authors: E. D. Kaverzneva; A. S. Salova;

doi: 10.1007/bf00917382

Mechanism of the oxidation of cellulose with nitrogen oxides

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Abstract

1. Enhanced formation of nitric esters in the oxidation of cellulose with nitrogen oxides occurs when N2O3 is absent from the oxidizing mixture. 2. A maximum rate of oxidation of cellulose by N2O4 is attained at a definite content of NO in the mixture of oxides, and under the conditions applying in this investigation this NO content was 7–10%. 3. A scheme of the oxidation mechanism is proposed in explanation of these facts.

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Russian Academy of Sciences
Russian Federation

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