Vapor-phase catalytic alkylation of benzene with alkenes Communication 3. Alkylation of benzene with 1-pentene

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1959 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 8, pages 279-281 (issn: 0568-5230, eissn: 1573-9171,

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Authors: N. I. Shuikin; N. A. Pozdnyak;

doi: 10.1007/bf00917374

Vapor-phase catalytic alkylation of benzene with alkenes Communication 3. Alkylation of benzene with 1-pentene

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Abstract

1. It was found that, in the alkylation of benzene with 1-pentene at 350° under a pressure of 40 atm in presence of zinc chloride supported on alumina,(1, 1-dimethylpropyl)benzene was formed instead of the expected (1-methylbutyl)- and pentyl-benzenes. 2. Under these conditions 1-pentene is isomerized to 2-methyl-1-butene and 2-methyl-2-butene, which are then hydrogenated partially to isopentane.

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Russian Academy of Sciences
Russian Federation

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