Isotopic exchange between methyl iodide and iodine

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1959 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 8, pages 227-230 (issn: 0568-5230, eissn: 1573-9171,

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Authors: V. B. Miller; M. B. Neiman; S. P. Solodovnikov;

doi: 10.1007/bf00917365

Isotopic exchange between methyl iodide and iodine

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Abstract

1. We have developed a method for the separation of I2 from CH3I based on the adsorption of iodine vapor on silver. 2. In the 30–45° temperature range the isotopic exchange between CH3l*and I2 proceeds on the walls of the reaction vessel. 3. Addition of oxygen has no effect on the rate of isotopic exchange.

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Russian Academy of Sciences
Russian Federation

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