Free-radical addition of primary alcohols to unsaturated alcohols

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1962 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 11, pages 831-834 (issn: 0568-5230, eissn: 1573-9171,

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Authors: G. I. Nikishin; V. D. Vorob'ev;

doi: 10.1007/bf00905312

Free-radical addition of primary alcohols to unsaturated alcohols

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Abstract

1. Reaction, initiated by t-butyl peroxide, between normal primary alcohols and unsaturated alcohols with the double bond in the allyl position leads to 1,4-alkanediols. 2. At molar proportions of saturated alcohol: allyl alcohol: peroxide of 20:1: 0.2–0.3, a reaction time of six hours, and a temperature of 160–170° the yields of 1∶1 adducts range from 50 to 60%.

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Russian Academy of Sciences
Russian Federation

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