Telomerization of octamethylcyclotetrasiloxane with dichloromethyl (3,3,3-trif luoropropyl) silane and with chlorotris (3,3,3-trif luoropropyl) silane

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1966 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences, USSR Division of Chemical Science, volume 15, pages 2,056-2,060 (issn: 0568-5230, eissn: 1573-9171,

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Authors: V. A. Ponomarenko; N. M. Khomutova;

doi: 10.1007/bf00867698

Telomerization of octamethylcyclotetrasiloxane with dichloromethyl (3,3,3-trif luoropropyl) silane and with chlorotris (3,3,3-trif luoropropyl) silane

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Abstract

1. The telomerization of octamethylcyclotetrasiloxane with fluorinated alkylchlorosilanes was investigated for the first time. The telomerization of octamethylcyclotetrasiloxane with dichloromethyl (3,3,3-trifluoropropyl) silane and with chlorotris (3,3,3-trifluoropropyl) silane leads to the formation of linear structure. 2. The telomerization of octamethylcyclotetrasiloxane with chlorotris (3,3,3-trifluoropropyl) silane is accompanied by a side reaction in which terminal groups of the telomer are eliminated with formation of hexakis (3,3,3-trifluoropropyl) disiloxane.

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Russian Academy of Sciences
Russian Federation

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