Time-temperature superposition for partially crystalline polymers (polytetrafluoroethylene)

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1976 English Publisher:Springer Science and Business Media LLCJournal:Polymer Mechanics, volume 11, pages 340-346 (issn: 0032-390X, eissn: 1573-8922,

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Authors: A. Ya. Gol'dman; A. N. Grinman; Yu. F. Dunichev;

doi: 10.1007/bf00863978

Time-temperature superposition for partially crystalline polymers (polytetrafluoroethylene)

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Abstract

Time-temperature superposition in the\(\mathop \varepsilon \limits^.\) = const regime can be applied to partially crystalline fluoroplastics with different specific volumes. There is a correlation between the variation of the specific volume and the relaxation processes in fluoroplastics. Time-temperature superposition is valid only in the temperature regions between transitions. The master curves are theoretically described by means of a nonlinear equation.

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