Iododemercuration of unsymmetrical organomercury compounds

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1971 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 20, pages 1,491-1,493 (issn: 0568-5230, eissn: 1573-9171,

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Authors: I. P. Beletskaya; L. V. Savinykh; O. A. Reutov;

doi: 10.1007/bf00857430

Iododemercuration of unsymmetrical organomercury compounds

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Abstract

1. A study was made of the kinetics of the iododemercuration of organomercury compounds, containing strong electron-acceptor substituents, in dimethylformamide and in benzene. 2. The increase in the rate of the iododemercuration reaction in the discussed series of organomercury compounds proceeds symbatically with increase in the stability of the carbanion, entering into the composition of the organomercury compound.

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Lomonosov Moscow State University
Russian Federation

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