Tetrabutylammonium borohydride and its complex with aluminum borohydride

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1971 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 20, pages 1,266-1,268 (issn: 0568-5230, eissn: 1573-9171,

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Authors: L. V. Titov; L. A. Gavrilova; E. R. Eremin; S. S. Mishchenchuk; V. Ya. Rosolovskii;

doi: 10.1007/bf00855404

Tetrabutylammonium borohydride and its complex with aluminum borohydride

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Abstract

1. Tetrabutylammonium borohydride was obtained by the exchange reaction of tetrabutylammonium bromide with excess sodium borohydride in ether isopropyl alcohol or benzene medium. 2. Tetrabutylammonium borohydride aluminate, [(C4H9)4N] [Al(BH4)4], was synthesized by the reaction of the tetrabutylammonium and aluminum borohydrides. 3. In the series of complex hydrides, containing the anions BH 4 − and [Al(BH4)4]− and the cation [R4N]+, the solubility in nonpolar solvents increases in a steady manner, while the melting point decreases, with increase in the length of the hydrocarbon chain R.

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Russian Academy of Sciences
Russian Federation

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