Hydrogenation and isomerization of allyl alcohol and 3-cyclohexenol in presence of the chloromethyl methyl sulfoxide complexes of palladium and rhodium

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1973 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 22, pages 687-688 (issn: 0568-5230, eissn: 1573-9171,

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Authors: L. Kh. Freidlin; Yu. A. Kopyttsev; N. M. Nazarova;

doi: 10.1007/bf00854068

Hydrogenation and isomerization of allyl alcohol and 3-cyclohexenol in presence of the chloromethyl methyl sulfoxide complexes of palladium and rhodium

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Abstract

1. The chloromethyl methyl sulfoxide complex of Pd catalyzes the hydrogenation of the C=C bond of allyl alcohol (AA) and 3-cyclohexenol, and also their rearrangement respectively to propionaldehyde and cyclohexanone. 2. The chloromethyl methyl sulfoxide complex of Rh accelerates the hydrogenation of AA and also its rearrangement, either with the involvement of hydrogen or in its absence. 3. The Rh complex catalyzes the reduction of propionaldehyde, but it is poisoned by acrolein. In contrast, the Pd complex accelerates the hydrogenation of acrolein, but is inert toward propionaldehyde.

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Russian Academy of Sciences
Russian Federation

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