Chemiluminescence in the autooxidation of dihydroxyphenylalanine

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1972 English Publisher:Springer Science and Business Media LLCJournal:Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, volume 21, pages 2,637-2,640 (issn: 0568-5230, eissn: 1573-9171,

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Authors: G. N. Bogdanov; V. N. Shtol'ko;

doi: 10.1007/bf00849829

Chemiluminescence in the autooxidation of dihydroxyphenylalanine

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Abstract

1. In the oxidation of dihydroxyphenylalanine in alkaline medium, chemiluminescence was detected in the region of 450–600 nm with a maximum at 530 nm. The step of cyclization, leading to the formation of 5,6-dihydroxyindole, proved responsible for the luminescence. 2. The kinetic curve of the change in the luminescence is described by a second-order equation of autocatalysis.

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Russian Academy of Sciences
Russian Federation

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